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Method of production of alcohols by catalytic hydrogenation of acid levulinic in a step

机译:在一个步骤中通过酸乙酰丙酸的催化加氢生产醇的方法

摘要

The present invention relates to a process for conversion of a load comprising levulinic acid mono - alcohol, in the presence of hydrogen, the said process operating in a step, at a temperature of between 80°C. and 250°C, at a pressure ranging from 0,5 and 20 mpa, and in the presence of a catalyst comprising a metal of groups 7 to 10 chosen from the plate (pt), the ruthenium (uk), the iridium (ir), rhenium (re), said metal being used alone and a support selected from among titanium oxide (tio2), zirconium oxide (zro2), and the silica (sio2), taken alone or in mixture. The process according to the invention makes it possible to obtain the butanol, and preferably of the 2 - butanol with a selectivity of greater than 15% molar,
机译:本发明涉及在氢存在下转化包含乙酰丙酸单醇的负载物的方法,所述方法在80℃之间的步骤中操作。在250°C和250°C的压力下,压力介于0.5和20 mpa之间,并且在存在选自板(pt),钌(uk),铱(ir ),re(re),所述金属可单独使用或混合使用,所述金属可单独使用,以及选自氧化钛(tio2),氧化锆(zro2)和二氧化硅(sio2)的载体。根据本发明的方法使得可以得到丁醇,并且优选以大于15%摩尔的选择性获得2-丁醇。

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