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Glass fiber sizing agent, glass fiber for fiber reinforced resin, and fiber reinforced synthetic resin composition containing aqueous polyurethane resin composition

机译:玻璃纤维上浆剂,用于纤维增强树脂的玻璃纤维以及包含水性聚氨酯树脂组合物的纤维增强合成树脂组合物

摘要

PROBLEM TO BE SOLVED: To provide an aqueous polyurethane resin composition capable of providing a glass fiber reinforced resin excellent in binding properties for glass fibers and in mechanical strength.SOLUTION: An aqueous polyurethane resin composition is obtained by dispersing in water an aqueous polyurethane resin which includes a polyol compound (A), polyisocyanate (B), a hydrophilic compound (C), fatty acid ester polyol (D), and a compound (E) with a hydroxyl group and an unsaturated double bond. (C) is a compound represented by general formula (1) wherein Ris a 2-4 valent alcohol residue or a group represented by general formula (2). (D) is a fatty acid ester polyol containing an unsaturated fatty acid ester polyol obtained by reacting a fatty acid of a drying oil or a fatty acid of semidrying oil with trimethylolpropane, glycerin or pentaerythritol. (E) is an allyl ether compound, a (meth)acrylate compound, a vinyl ether compound or an alkyl vinyl ether compound.
机译:解决的问题:提供一种水性聚氨酯树脂组合物,其能够提供对玻璃纤维的粘合性和机械强度优异的玻璃纤维增​​强树脂。解决方案:水性聚氨酯树脂组合物是通过将水性聚氨酯树脂分散在水中而获得的。包括多元醇化合物(A),多异氰酸酯(B),亲水性化合物(C),脂肪酸酯多元醇(D)和具有羟基和不饱和双键的化合物(E)。 (C)是由通式(1)表示的化合物,其中R 1s为2-4价的醇残基或由通式(2)表示的基团。 (D)是包含不饱和脂肪酸酯多元醇的脂肪酸酯多元醇,该不饱和脂肪酸酯多元醇通过使干燥油的脂肪酸或半干燥油的脂肪酸与三羟甲基丙烷,甘油或季戊四醇反应而获得。 (E)为烯丙基醚化合物,(甲基)丙烯酸酯化合物,乙烯基醚化合物或烷基乙烯基醚化合物。

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