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CATHODE ACTIVE MATERIAL FOR NON-AQUEOUS ELECTROLYTE RECHARGEABLE BATTERY AND MANUFACTURING METHOD FOR SAME, AND NON-AQUEOUS ELECTROLYTE RECHARGEABLE BATTERY
CATHODE ACTIVE MATERIAL FOR NON-AQUEOUS ELECTROLYTE RECHARGEABLE BATTERY AND MANUFACTURING METHOD FOR SAME, AND NON-AQUEOUS ELECTROLYTE RECHARGEABLE BATTERY
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机译:非水电解液可充电电池的阴极活性材料及其制造方法和非水电解液可充电电池
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摘要
To provide a cathode active material for a non-aqueous electrode rechargeable battery, with which it is possible to improve input/output characteristics, particularly by reducing resistance in a low SOC state in which DCIR increases, and to provide a manufacturing method for same. The cathode active material includes layered hexagonal crystal lithium nickel manganese composite oxide particles represented by the general formula (A): Li1+uNixMnyCozMtO2 (where 0≦u≦0.20, x+y+z+t=1, 0.30≦x≦0.70, 0.10≦y≦0.55, 0≦z≦0.40, 0≦t≦0.10, and M is one or more elements selected from Al, Ti, V, Cr, Zr, Nb, Mo, and W), and further including Na, Mg, Ca and SO4, in which the total amount of Na, Mg and Ca is 0.01 to 0.1 mass %, the amount of SO4 is 0.1 to 1.0 mass %, and the ratio of the integrated intensity of the diffraction peak on plane (003) to that on plane (104) obtained by powder X-ray diffraction measurement using CuKα rays is 1.20 or greater.
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机译:本发明提供一种非水电极二次电池用正极活性物质,尤其是通过降低DCIR增加的低SOC状态下的电阻,可以提高输入输出特性,并提供其制造方法。正极活性材料包括由通式(A)表示的层状六方晶体锂镍锰复合氧化物颗粒:Li 1 + u Sub> Ni x Sub> Mn y Sub> Co z Sub> M t Sub> O 2 Sub>(其中0≦u≦0.20,x + y + z + t = 1,0.30≦x ≤0.70、0.10≤y≤0.55、0≤z≤0.40、0≤t≤0.10,并且M是选自Al,Ti,V,Cr,Zr,Nb,Mo和W中的一种或多种元素,并且进一步是包括Na,Mg,Ca和SO 4 Sub>,其中Na,Mg和Ca的总量为0.01至0.1质量%,SO 4 Sub>的量为0.1至0.1通过使用CuKα射线的粉末X射线衍射测定得到的平面(003)与平面(104)上的衍射峰的积分强度之比为1.0质量%,为1.20以上。
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