MESOSCOPIC MATERIALS COMPRISED OF ORDERED SUPERLATTICES OF MICROPOROUS METAL-ORGANIC FRAMEWORKS

摘要

The disclosure provides for MOF heterolites comprised of ordered superlattices of MOFs, the manufacture thereof, and the use of the MOF heterolites for various applications, such as gas separation and/ or storage, catalysis, light harvesting, and meta-materials. The MOFs are comprised of a plurality of linked M-X-L units, wherein M is a metal, metal ion, or metal containing complex; X and L are both an organic linking ligand. Preferred linking ligands are: