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Sulfur doped porous carbon catalyst and preparing method thereof

机译:硫掺杂多孔碳催化剂及其制备方法

摘要

The present invention provides a method for preparing a sulfur-doped porous carbon catalyst, the method comprising: a first step of forming a composite in a powder form by mixing a metal salt including transition metal and nitrogen, a precursor including sulfur, and a silica template together; a second step of forming crystalline carbon by heating the composite in inert gas; and a third step of forming a carbon catalyst having a porous structure by washing the crystalline carbon with an acid. Accordingly, the sulfur-doped porous carbon catalyst is used as a cathode electrode in a polymer electrolyte fuel cell and exhibits the same electrode activity as a commercialized platinum catalyst even when an expensive platinum catalyst is not used, thereby considerably increasing efficiency of the fuel cell. Furthermore, activity of a conventional cathode electrode using platinum rapidly decreases in an acid condition, whereas activity of an electrode can be maintained for a long period of time when a shape of a carbon catalyst is changed.
机译:本发明提供一种制备硫掺杂的多孔碳催化剂的方法,该方法包括:通过混合包括过渡金属和氮的金属盐,包括硫的前体和二氧化硅形成粉末形式的复合物的第一步。一起模板通过在惰性气体中加热复合物形成结晶碳的第二步骤;第三步骤是通过用酸洗涤结晶碳来形成具有多孔结构的碳催化剂。因此,硫掺杂的多孔碳催化剂被用作聚合物电解质燃料电池中的阴极,并且即使不使用昂贵的铂催化剂也表现出与商业化铂催化剂相同的电极活性,从而大大提高了燃料电池的效率。 。此外,使用铂的常规阴极电极的活性在酸性条件下迅速降低,而当碳催化剂的形状改变时,可以长时间维持电极的活性。

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