首页> 外国专利> LOW-VISCOSITY SOLUTIONS OF ALKALINE-EARTH METAL ALKOXIDES IN APROTIC SOLVENTS, METHOD FOR THE PRODUCTION OF SAME AND USE FOR THE PRODUCTION OF ZIEGLER-NATTA CATALYSTS.

LOW-VISCOSITY SOLUTIONS OF ALKALINE-EARTH METAL ALKOXIDES IN APROTIC SOLVENTS, METHOD FOR THE PRODUCTION OF SAME AND USE FOR THE PRODUCTION OF ZIEGLER-NATTA CATALYSTS.

机译:非质子传递溶剂中碱土金属低粘度溶液的制备方法及制备方法,可用于齐格勒-纳塔催化剂。

摘要

The invention relates to concentrated low-viscosity solutions of alkaline earth alkoxide compounds M(OCH2R6)2-a-b(OR7) a[O(CHR8)nOR9]b in a mixture of a metal alkyl compound M(R10R11) in aprotic solvents, where M is an alkaline-earth metal chosen from Mg, Ca, Ba, Sr; OCH2R6 is an alkoxide radical comprising at least 3 and at most 40 carbon atoms having a branch in position 2 in relation to the O function, thus R6 = -CHR12R13 with R12, R13 = mutually independent alkyl radicals C1-C18; R7 is an alkyl radical having 2-15 carbon atoms, which is either linear or has a branch in a position = 3 (in relation to the O function); R8 is an alkyl radical comprising 1 -6 carbon atoms, which is either linear or has a branch in a position = 3 (in relation to the O function); R9 has an alkyl radical with 2-15 carbon atoms, which is either linear or has a branch; R10 and R11 are any alkyl radicals comprising 1-15 carbon atoms, n = an integer from 1 to 4, a + b = 2, wherein a and b can assume values from 0 to 2 and the molar ratio of M(OCH2R6)2-a-b(OR7) a[O(CHR8)nOR9]b to M(R10R11) lies from 99.5:0.5 to 60:40.
机译:本发明涉及在非质子溶剂中的碱金属醇盐化合物M(OCH2R6)2-ab(OR7)a [O(CHR8)nOR9] b在金属烷基化合物M(R10R11)的混合物中的浓缩低粘度溶液,其中M是选自Mg,Ca,Ba,Sr的碱土金属。 OCH 2 R 6是包含至少3个且至多40个碳原子的烷氧基,其相对于O官能团在2位具有分支,因此R 6 = -CHR 12 R 13和R 12,R 13 =相互独立的烷基C 1 -C 18; R7是具有2-15个碳原子的烷基,其为直链或在≥3的位置(相对于O官能团)具有支链; R8是包含1 -6个碳原子的烷基,其为直链或在≥3的位置(相对于O官能团)具有支链; R9具有一个具有2-15个碳原子的烷基,该烷基为直链或支链; R 10和R 11是包含1-15个碳原子的任何烷基,n = 1至4的整数,a + b <= 2,其中a和b的取值范围为0至2,且摩尔比为M(OCH2R6) 2-ab(OR7)a [O(CHR8)nOR9] b至M(R10R11)为99.5:0.5至60:40。

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