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Ligands and rare earth complexes

机译:配体和稀土配合物

摘要

Provided is a novel rare earth complex which exhibits compatibility with a polymer or the like, and which has a glass transition temperature. Also provided are: a ligand for forming the rare earth complex; a rare-earth-complex production method; and a use of the rare earth complex. This ligand is a compound represented by general formula (1), namely X1-L1-Ar-L2-X2 (in general formula (1): Ar represents an aromatic heterohydrocarbon group or an aromatic hydrocarbon group; L1 and L2, which are bonded to Ar, are bonded so as form an angle with Ar at the center within the molecule; L1 and L2 independently represent linkers; and X1 and X2 independently represent a phosphoryl group represented by O=P(Ar11Ar12)- (with the caveat that Ar11 and Ar12 independently represent a substituted or unsubstituted aryl group, a substituted or unsubstituted heteroaryl group, or a substituted or unsubstituted aralkyl group)). Provided is a complex provided with a cluster structure including the aforementioned compound and a rare earth element.
机译:提供一种新型的稀土配合物,其与聚合物等具有相容性,并具有玻璃化转变温度。还提供了:用于形成稀土配合物的配体;稀土复合生产方法;以及稀土配合物的用途该配体是通式(1)表示的化合物,即X 1 -L 1 -Ar-L 2 -X 2(通式(1):Ar表示芳香族杂烃基或芳香族烃基; L 1和L 2相互键合)。与Ar形成键,从而与Ar在分子内的中心形成一个角度; L1和L2独立表示接头; X1和X2独立表示由O = P(Ar11Ar12)-表示的磷酰基且Ar 12独立地表示取代或未取代的芳基,取代或未取代的杂芳基或取代或未取代的芳烷基)。提供一种复合物,其具有包括上述化合物和稀土元素的簇结构。

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