Espirocu00cdclicos derivatives and their use in the Battle of Invertebrate pests

摘要

Compositions that include combinations of active compounds which includeAnd their use to protect against attack or growing plants infested by pests in addition, Invertebrates, Seeds comprising such compounds.Claim 1: Spiro compounds with the formula (1) wherein X is s or chu2082; W - Z are # - chu2082 - or * - # - chu2082 - S (o) or # u2099 - * - C (= o) - O - *, where the link # Brand W, phenyl and *,The Link of azetidine Z; n is 0, 1 or 2; ru00b9 halometilo; ru00b2u1d43 Halogen, halometilo, halometoxi; ru00b2u1d47, ru00b2u1d9c are independently H or as defined for ru00b2u1d43; ru00b3 cu2081u208bu2086 is selected from h, alkyl,Cu2081u208bu2086 - haloalquilo, cu2082u208bu2086 - alquenilo, cu2082u208bu2086 - haloalquenilo, cu2082u208bu2086 - alquinilo, cu2082u208bu2086 - haloalquinilo aliphatic groups, whose are unsubstituted or substituted with one or more ru00b3u00b9 cycloalkyl Radicals; cu2083u208bu2086 -,Cu2083u208bu2086 - halocicloalquilo whose cyclic groups are unsubstituted or substituted with one or more radical ru00b3u00b2; C (= o) n (ru00b3u2074 ru00b3u00b3), N (ru00b3u00b3) ru00b3u2075, CH = noru00b3u2076; phenyl Heterocycles or hetarilo,The Rings are not replaced, or partially or totally replaced with ra; ru00b3u00b9 is independently cu2081u208bu2086 Oh, cyano -, alkoxy, cu2081u208bu2086 - haloalcoxi, S (OR) u2099 cu2081u208bu2086 alkyl -, S - (OR) - u2099 cu2081u208bu2086 haloalquilo,C (= o) n (ru00b3u00b3) ru00b3u2074, cycloalkyl or cu2083u208bu2086 - cu2083u208bu2086 - halocicloalquilo, whose cycles are unsubstituted or substituted with one or more ru00b3u00b9u00b9; or phenyl Heterocycles or hetarilo, whose rings are not replaced,Or partially or totally replaced with ra; ru00b3u00b9u00b9 is Regardless, Oh, cyano -, alkyl - or cu2081u208bu2082 cu2081u208bu2082 haloalquilo; ru00b3u00b3 is H or alkyl cu2081u208bu2086; ru00b3u2074 cu2081u208bu2086 is H, alkyl, cu2081u208bu2086 - haloalquilo, cu2082u208bu2086 - alquenilo,Cu2082u208bu2086 haloalquenilo cu2082u208bu2086 alquinilo -, -, - or - cu2082u208bu2086 haloalquinilo cu2083u208bu2086 cycloalkyl, cu2083u208bu2086 - halocicloalquilo, cu2083u208bu2086 - cicloalquilmetilo or cu2083u208bu2086 - halocicloalquil - MethylThe Rings are unsubstituted or substituted with a cyano; ru00b3u2075 cu2081u208bu2086 h, alkyl, cu2081u208bu2086 - haloalquilo, cu2082u208bu2084 - alquenilo, cu2082u208bu2084 alquinilo chu2082 -, - CN, - cu2083u208bu2086 cycloalkyl, cu2083u208bu2086 - halocicloalquilo,Cu2083u208bu2086 - cicloalquilmetilo, cu2083u208bu2086 - halocicloalquilmetilo, phenyl and hetarilo, the Aromatic rings are not replaced, or partially or totally replaced with ra ru00b3u00b2 is independently;Cu2081u208bu2086 alkyl, cu2081u208bu2086 - haloalquilo or group as defined for ru00b3u00b9; ru00b3u2076 is independently cu2081u208bu2086 h, alkyl or cu2081u208bu2086 - haloalquilo; ra is selected independently of halogen, cyano, nou2082,Cu2081u208bu2084 alkyl, cu2081u208bu2084 - haloalquilo, cu2082u208bu2084 - alquenilo, cu2082u208bu2084 - haloalquenilo, cu2082u208bu2084 alquinilo cu2082u208bu2084 haloalquinilo -, -, - cu2083u208bu2086 cycloalkyl, cu2083u208bu2086 - halocicloalquilo, cu2081u208bu2084 - alkoxy -, cu2081u208bu2084 haloalcoxi, S (or u2099 cu2081u208bu2084 alkyl) -,S (o) u2099 - cu2081u208bu2084 - haloalquilo, cu2081u208bu2084 - alquilcarbonilo, cu2081u208bu2084 - haloalquilcarbonilo,C (= o) n (ru00b3u00b3) ru00b3u2074; or two ra present at the carbon atom of a saturated or partially saturated Ring can form together = = o or s; or two ra present in the same Ring Member s or osA Heterocyclic Ring May form a Group (n = cu2081u208bu2086 alkyl), (= Not cu2081u208bu2086 alkyl), NN = (H) (cu2081u208bu2086 alkyl) (OR = NN cu2081u208bu2086 alkyl u2082); and the n-oxides,These salts stereoisomers and acceptable in Agriculture and Veterinary Science.