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Process for the production of polymeric yarn high tenacity and low creep, polymeric or copolu00ecmericos yarn high tenacity and low creep, and use of polymeric yarn

机译:制备高强度,低蠕变的聚合物纱线,高强度,低蠕变的聚合物或共聚酯纱线的方法以及使用聚合物纱线

摘要

Process for the production of polymeric yarn high tenacity and low creep, polymeric or co polymeric yarn high tenacity and low creep, and use of polymeric yarns.The present invention relates to a process for the production of polymeric yarn high tenacity and low creep, which comprises the following steps: (a) preparing a mixture of: (I) a first polymer or copolymer poliolefinico of ultra high molecular weight, (II) a second polymer. Or a copolymer poliolefmico nanocompu00f3sito clay, (III) a solvent for spinning apolar,(b) feeding the resulting suspension in an extruder at a temperature of at least 180 u00b0 C to form a gel, (c) spinning the gel obtained in a chain with ratio of length / diameter (L / D) greater than 15, (d) subjecting the wire to a cooling to a temperature below 2 u00b0 C, (and later) Removal of the solvent spinning apolar,And (f) to stretch the wire obtained by achieving tenacity more than 18 CN / dtex and a fluence lower than 0,07% per hour, and the first polymer or copolymer poliolefinico of ultra high molecular weight has a weight average molecular weight greater than 2000.000 g / mol and a polidispersividade above 7, and the second polymer or copolymer poliolefinico nanocompu00f3sito clay is obtained by polymerization of an olefin and a III situ lamellar clay exfoliated, and polyolefin obtained has a weight average molecular weight of at least 400. 000 g / mol.
机译:制备高强度低蠕变的聚合物纱线的方法,高强度和低蠕变的聚合物或共聚合物纱线以及聚合物纱线的用途。本发明涉及制备高强度和低蠕变的聚合物纱线的方法,该方法包括以下步骤:(a)制备以下混合物:(I)超高分子量的第一聚合物或共聚物聚烯烃,(II)第二聚合物。或共聚物poliolefmico nanocomp sito粘土,(III)非极性纺丝的溶剂,(b)将所得悬浮液在至少180°C的温度下进料到挤出机中形成凝胶,(c)纺丝得到的凝胶在长度/直径比(L // D)大于15的链中,(d)将金属丝冷却至低于2 C的温度,然后去除非极性旋转的溶剂,并且(f)拉伸通过获得大于18 CN / dtex的强度和每小时低于0.007%的通量而获得的金属丝,并且超高分子量的第一聚合物或共聚物聚烯烃具有的重均分子量大于2000.000 g / mol和大于7的聚丙烯酸酯分散体,并且第二种聚合物或共聚物聚丙烯烯纳米复合粘土是通过烯烃和脱落的III位层状粘土的聚合而获得的,并且所得聚烯烃的重均分子量至少为400 .000克/摩尔

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