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Process for hydrotreating a hydrocarbon cut of boiling point above 250 u00b0 C in the presence of a sulfide catalyst prepared by means of a cyclic oligosaccharides

机译:在借助于环状低聚糖制备的硫化物催化剂存在下,对沸点高于250℃的烃馏分进行加氢处理的方法

摘要

Process for hydrotreating a hydrocarbon cut of boiling point above 250 u00b0 C in the presence of a sulfide catalyst prepared by means of a cyclic oligosaccharides.The present invention relates to a process for the preparation of a catalyst comprising at least a metal of Group VIII, a metal of Group VIB at least, and at least one support.Comprising successively: (I) at least one of the stages selected from: I1) a step of placing in contact of the pre catalyst comprising the metal of Group VIII,This metal from Group VIB and this support with cyclic oligosaccharides composed of at least six subunits glicopiranose connected in 244 - (1)4); 2) a step of placing the support with a solution containing at least a precursor of at least this metal of Group VIII,And a metal of Group VIB and precursos of a cyclic oligosaccharides composed of at least 6 subunits glicopiranose connected in 244 - (1)2); and I3) a first stage of placing in contact of the support with a cyclic oligosaccharides composed of at least 6 subunits glicopiranose connected in 244 - ()4) followed by a second step of placing in contact of the solid from this first stage with a precursor of metal of Group VIII, and a precursor of the metal from Group VIB; (II) a stage of droughtGem; (III) a step of heat treatment.
机译:在通过环状低聚糖制备的硫化物催化剂存在下,对沸点高于250℃的烃馏分进行加氢处理的方法。本发明涉及一种至少包含第VIII族金属的催化剂的制备方法。 ,至少一种VIB族金属和至少一种载体。依次包括:(I)选自以下的至少一个步骤:I1)使包含VIII族金属的预催化剂接触的步骤,来自VIB族的金属,并以环状低聚糖为载体,该环状低聚糖由至少六个亚基古朴糖的亚基组成,连接在<244>-(1)4)中; 2)将支撑物置于至少含有至少一种VIII族金属的前体,VIB族金属和环状寡糖的前体的溶液中,该环状寡糖由连接在<244>中的至少6个古扁皮糖组成- (1)2);和I3)第一步,使载体与环状寡糖接触,该环状寡糖由连接在<244>-(4)中的至少6个亚基葡糖醛糖组成,然后是第二步,第二步是使固体接触具有VIII族金属的前体和VIB族金属的前体; (二)干旱宝石阶段; (III)热处理步骤。

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