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Chiral pyrrolidinium salt with a fragment of natural terpene and method for producing chiral pyrrolidinium salt with a fragment of natural terpene
Chiral pyrrolidinium salt with a fragment of natural terpene and method for producing chiral pyrrolidinium salt with a fragment of natural terpene
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机译:具有天然萜烯片段的手性吡咯烷鎓盐和制备具有天然萜烯片段的手性吡咯烷鎓盐的方法
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摘要
the object of the application is chiralna pirolidyniowa salt with a natural terpenu, presented in the general formula, which is in part of the cation, with czwartorzędowym nitrogen atom.chiralny substituent [(1r endo) - 1,3,3 - trimethylbicyclo [2.2.1] hept-2-en - 2 - methyl naphthalen-1-yloxy), which is a (+) - fencholu and part anionową represents anion chloridic.the application also includes a way to produce chiralnej salt pirolidyniowej with a natural terpenu,of reaction of alcohol terpenowego with n - (2-hydroxyethyl) pirolidyną when mole ratio of from 1.0 to 1.1 in an anhydrous diethyl etherat a temperature between 15 oc - or freeze during the 8 - 24 hours, characterised by the fact that leads to reaction (1r endo) - 2 - chlorometoksy - 1,3,3 - trimetylobicyclo [2.2.1] heptane (derived from (+) - fencholu) with n - (2-hydroxyethyl) pirolidyną receiving as chloride product n - (2-hydroxyethyl) - n - [((1r endo) - 1,3,3 - trimetylobicyclo [2.2.1] hept-2-en - 2 - naphthalen-1-yloxy) methyl] pyrrolidinium.
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