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Method for synthesizing ionic complex, electrolytic solution for non-aqueous electrolyte battery, non-aqueous electrolyte battery and ionic complex

机译:离子络合物的合成方法,非水电解质电池用电解液,非水电解质电池和离子络合物

摘要

To provide a material suitable for a nonaqueous electrolyte battery having high-temperature durability. An ionic complex of the present invention is represented by any of the following formulae (1) to (3). For example, in the formula (1), A is a metal ion, a proton, or an onium ion; M is any of groups 13 to 15 elements. R 1 represents a hydrocarbon group which may have a ring, a heteroatom, or a halogen atom, the hydrocarbon group having 1 to 10 carbon atoms, or -N(R 2 )-. R 2 at this time represents hydrogen, alkali metal, a hydrocarbon group which may have a ring, a heteroatom, or a halogen atom, the hydrocarbon group having 1 to 10 carbon atoms. R 2 can also have a branched chain or a ring structure when the number of carbon atoms is 3 or more. Y is carbon or sulfur. When Y is carbon, r is 1. When Y is sulfur, r is 1 or 2. a is 1 or 2, o is 2 or 4, n is 1 or 2, p is 0 or 1, q is 1 or 2, and r is 0, 1 or 2. When p is 0, a direct bond is formed between S and Y.
机译:提供适合于具有高温耐久性的非水电解质电池的材料。本发明的离子络合物由下式(1)至(3)中的任何一个表示。例如,在式(1)中,A为金属离子,质子或鎓离子。 M是13至15族的任何一个。 R 1表示可以具有环,杂原子或卤素原子的烃基,具有1至10个碳原子的烃基或-N(R 2)-。此时的R 2表示氢,碱金属,可以具有环,杂原子或卤原子的烃基,该烃基具有1至10个碳原子。当碳原子数为3以上时,R 2也可以具有支链或环结构。 Y是碳或硫。当Y为碳时,r为1。当Y为硫时,r为1或2。a为1或2,o为2或4,n为1或2,p为0或1,q为1或2, r为0、1或2。当p为0时,在S和Y之间形成直接键。

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