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Catalyst for hydrosilylation reaction, hydrogenation reaction and hydrosilane reduction reaction

机译:用于氢化硅烷化反应,氢化反应和氢化硅烷还原反应的催化剂

摘要

It comprises a compound of the formula (1) and comprises at least one reaction selected from a hydrosilylation reaction or hydrogenation reaction on an aliphatic unsaturated bond and a hydrosilane reduction reaction on a carbon-oxygen unsaturated bond or a carbon-nitrogen unsaturated bond. Active catalyst. Mn (L) m (1) {M is Fe, Co, or Ni having an oxidation number of 0, L is an isocyanide ligand represented by the following formula (2), n is an integer of 1 to 8, m represents an integer of 2 to 12. (CN) x-R1 (2) (R1 may be substituted with a halogen atom, and one or more atoms selected from O, N, S and Si may be present. Represents a 1 to 3 valent organic group, and x represents an integer of 1 to 3.)
机译:它包含式(1)的化合物,并且包含至少一种选自脂族不饱和键的氢化硅烷化反应或氢化反应和碳-氧不饱和键或碳-氮不饱和键的氢化硅烷还原反应的至少一种反应。活性催化剂。 Mn(L)m(1){M为氧化数为0的Fe,Co或Ni,L为下式(2)表示的异氰酸酯配体,n为1至8的整数,m表示(CN)x-R1(2)(R1可以被卤素原子取代,并且可以存在一个或多个选自O,N,S和Si的原子。代表1至3价有机组,x表示1到3的整数。)

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