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Method of manufacturing polyarylene sulfide, and polyarylene

机译:聚芳撑硫醚的制造方法以及聚芳撑芳烃

摘要

To provide a method of manufacturing polyarylene sulfide (PAS) while efficiently recovering an organic amide solvent at a low energy cost, without using an organic solvent, from washing wastewater produced by washing a raw material mixture containing PAS and an organic amide solvent using a solvent containing water; a method of manufacturing PAS by reducing the amount of water supplied when washing the raw material mixture using a solvent containing water; and PAS manufactured by these methods. A method according to the present invention includes: a step of mixing a solvent containing water and a raw material mixture that contains PAS and an organic amide solvent, and then washing the PAS; a step of obtaining a separated liquid by solid-liquid separation; and a step of separating the separated liquid into distilled vapor having a smaller amount of the organic amide solvent and a recovered liquid having a larger amount of the organic amide solvent by heating, where the heating is performed utilizing an increase in temperature based on compressing the distilled vapor and/or compressing a heat medium heat-exchanged with the distilled vapor.
机译:提供一种制造聚芳撑硫醚(PAS)的方法,同时无需使用有机溶剂就能以较低的能源成本有效回收有机酰胺溶剂,该洗涤废水是通过用溶剂洗涤包含PAS和有机酰胺溶剂的原料混合物而产生的盛水通过减少在使用含水溶剂洗涤原料混合物时供应的水的量来制造PAS的方法;和通过这些方法制造的PAS。根据本发明的方法包括以下步骤:将含有水的溶剂与含有PAS和有机酰胺溶剂的原料混合物混合,然后洗涤PAS。通过固液分离得到分离液的步骤;以及通过加热将分离的液体分离成具有较少量的有机酰胺溶剂的蒸馏蒸气和具有大量的有机酰胺溶剂的回收液的步骤,其中加热是基于压缩溶剂而利用温度升高来进行的。蒸馏蒸气和/或压缩与蒸馏蒸气进行热交换的热介质。

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