Characteristics of PAHs in PM_(10) aerosols collected from different districts in Xiamen

摘要

2004年冬季在厦门市4个不同功能区连续10d采集并分析了PM10中16种优控多环芳烃(PAHs).研究发现,各个功能区大气PM10中多环芳烃总浓度(ΣPAHs)存在明显差别工业区(湖里)10.87~27.54ng·m-3、旅游区(鼓浪屿)7.79~21.14ng·m-3、居民区(洪文)6.52~13·39ng·m-3、森林区(小坪)5.20~11.43ng·m-3;但各个功能区PM10中各种PAH化合物的相对组成趋于一致,所占比例最高的前4种化合物为菲、芘、和芴,表明冬季不同功能区PM10中PAHs的主要污染来源在很大程度上相似或相同.根据典型污染来源中特征化合物比值如苯并(a)蒽/、荧蒽/芘和芘/苯并(a)芘及其有机碳/元素碳的值,推断厦门市PM10中的PAHs主要来源于汽车尾气的排放. 【英文摘要】 An intensive sampling program has been undertaken in the absence of precipitation at four different sites, Xiamen, to characterize the atmospheric concentration of 16 priority polycyclic aromatic hydrocarbons in PM_ 10 aerosols during 2004 winter. There was significant difference in the average value of ΣPAHs (defined as the sum of 16 PAH compounds) during the sampling time among four sites. ΣPAHs value is as follows: Huli at 10.9~27.5 ng·m -3 , Gulangyu at 7.8~21.1 ng·m -3 , Hongwen at 6.5~13.4 ng·m -3 , a...