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Application of Solvent Sublation for Removal of Toxic Organic Compounds from Aqueous Solution

机译:溶剂气浮法在去除水中有毒有机物中的应用

摘要

Removal of 12 organic compounds containing chloro-chemicals from an aqueous solution has been carried out using solvent sublation.The removal was obtaind to compare with the experimental results. The removal rate of organic compounds is strongly concerned with the physical and chemical properties of their compounds,such as solubility,vapor pressure,surface tension and distribution coefficient between the aqueous and organic phase.The experimental removal rate is evaluated and discussed concernig the physical and chemical properties of the compounds to be removed. A model for the removal mechanism is constracted by considering several terms such as adsorption on bubble,entrainment with boudary layer of bubble,vaporization to bubble and mass transfer to the organic solvent in the upper part of column.The calculated value is in good agreement with the experimental results.Accoding to the removal model,contribution percentage of the above terms is estimated and then it is clarified which terms are significant for the removal of the organic compounds with different chemical properties.
机译:使用溶剂升华法从水溶液中去除了12种含氯化合物的有机化合物,并与实验结果进行了比较。有机化合物的去除率与化合物的物理化学性质密切相关,如溶解度,蒸气压,表面张力和水相与有机相之间的分配系数。要去除的化合物的化学性质。通过考虑气泡吸附,气泡边界层夹带,汽化成气泡,传质到塔上部有机溶剂等几个方面,建立了去除机理的模型。根据去除模型,估算了上述项的贡献率,然后阐明了哪些项对去除具有不同化学性质的有机化合物具有重要意义。

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