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G′ band in double- and triple-walled carbon nanotubes: A Raman study

机译:双壁和三壁碳纳米管中的G'带:拉曼研究

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摘要

Double- and triple-walled carbon nanotubes are studied in detail by laser energy-dependent Raman spectroscopy in order to get a deeper understanding about the second-order G[superscript '] band Raman process, general nanotube properties, such as electronic and vibrational properties, and the growth method itself. In this work, the inner nanotubes from the double- and triple-walled carbon nanotubes are produced through the encapsulation of fullerene peapods with high-temperature thermal treatments. We find that the spectral features of the G[superscript '] band, such as the intensity, frequency, linewidth, and line shape are highly sensitive to the annealing temperature variations. We also discuss the triple-peak structure of the G[superscript '] band observed in an individual triple-walled carbon nanotube taken at several laser energies connecting its Raman spectra with that for the G[superscript '] band spectra obtained for bundled triple-walled carbon nanotubes.
机译:通过激光能量依赖性拉曼光谱对双壁和三壁碳纳米管进行了详细研究,以更深入地了解二阶G [带]带拉曼过程,一般的纳米管性质,例如电子和振动性质,以及生长方法本身。在这项工作中,双层和三层碳纳米管的内部纳米管是通过富勒烯豌豆球囊的高温热处理而制成的。我们发现,G [上标]带的光谱特征,例如强度,频率,线宽和线形对退火温度变化高度敏感。我们还讨论了在单个三壁碳纳米管中观察到的G [带]的三峰结构,这些碳纳米管是在几种激光能量下获得的,该能量将其拉曼光谱与为捆绑的三重碳纳米管所获得的G [带]谱进行了比较。壁碳纳米管。

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