Implementation of electric vehicle system based on solar energy in Singapore assessment of flow batteries for energy storage

摘要

For large-scale energy storage application, flow battery has the advantages of decoupled power and energy management, extended life cycles and relatively low cost of unit energy output ($/kWh). In this thesis, an overview of various flow battery technologies has been presented, with comparison to other energy storage technologies available in the market. It has been found that though flow batteries generally have lower energy density than other electro-chemical storage systems, the easy scalability of energy/power capacity at very low O&M cost enables flow batteries to be one of the fastest emerging energy storage technologies. The intellectual property landscape of current flow battery market has also been reviewed. The three dominating flow battery technologies in the market are Regenesys polysulfide/bromide redox flow battery (PBR), zinc/bromine battery (ZBB) and all vanadium redox flow battery (VRB). VRB has been chosen for an in-depth analysis of its design and technology, mainly because of its halogen-free operation and superior electrolyte properties. A cost model based on VRB system has been built in the context of Singapore, and the Capital Cost per Cycle (CCPC) for a 250kW VRB system with 8 hours of discharge duration is estimated to be about $0.0828/kWh. However, this figure changes considerably with the materials' costs, the design of electrolyte and cell stack, as well as the power and energy capacity of the system. Based on this cost model, it is also investigated in this thesis that in view of the current electricity prices, it is economically unfeasible to implement VRB system for bulk electricity price arbitrage in Singapore.