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Micro- and Nanostructural Characteristics of Particles Before and After an Exhaust Gas Recirculation System Scrubber.

机译:排气再循环系统洗涤器前后颗粒的微观和纳米结构特征。

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摘要

This work provides insight into the morphology and mixing state of submicron particles in diesel exhaust from a ship engine with an exhaust gas recirculation scrubber. Particles from this low-speed ship engine on test bed were collected using a microiner-tial impactor with transmission electron microscopy (TEM) grids on two stages. Micro- and nanostructural characteristics of sin-gle particles were studied by TEM. Image analysis was carried out on overview and high-resolution images, revealing influence of the exhaust gas treatment (scrubber) on the particle morphology and mixing state. Soot agglomerates were found to be collapsed after scrubber, reflected by their change in fractal dimension (fly) from 1.88 to 2.13. Soot was predominantly found internally mixed with other components, with a higher degree of internal mix-ing observed after scrubber. Soot nanostructural characteristics on the near atomic scale such as layer distance, lamella length, and tortuosity were not observed to be influenced by the scrub-ber. We also found that particles in the size range between 30 and 50 nm, which were abundant in the exhaust before and after scrubber, were not graphitic soot. Furthermore, we found indications that these particles are composed of other crystalline material (salts).
机译:这项工作提供了对带有排气再循环洗涤器的船舶发动机柴油机排气中亚微米颗粒形态和混合状态的深入了解。使用微惯性撞击器在两个阶段收集来自低速船用发动机在测试台上的颗粒,该撞击器带有透射电子显微镜(TEM)网格。用透射电子显微镜研究了单颗粒的微观和纳米结构特征。在概览图像和高分辨率图像上进行了图像分析,揭示了废气处理(洗涤塔)对颗粒形态和混合状态的影响。发现烟灰结块在洗涤后会坍塌,这是由它们的分形维数(蝇)从1.88变到2.13所反映的。烟灰主要与其他成分内部混合,洗涤后内部混合程度更高。未观察到烟灰纳米结构特征在近原子尺度上如层距,薄片长度和曲折度受洗涤器的影响。我们还发现,在洗涤器前后废气中富含的粒径在30至50 nm之间的颗粒不是石墨烟灰。此外,我们发现这些颗粒是由其他晶体材料(盐)组成的迹象。

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