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Solidification of Hypereutectic Thin Wall Ductile Cast Iron

机译:过共晶薄壁球墨铸铁的凝固

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摘要

Hypereutectic ductile iron was cast in green sand moulds with four plates with thickness of 1.5, 2, 3 and 4 mm in each mould. Temperatures were measured in the 3 and 4 mm plate. The temperature curves showed that eutectic solidification was divided into two stages: primary and secondary eutectic solidification. The first stage, which was relatively short, had none or very little recalescence. Further under cooling, followed by reheating during recalescence, was necessary to initiate the second part of the eutectic solidification. Both the secondary under cooling and recalescence was larger in the 3 mm plates than in the 4 mm plates. All 1.5 mm plates contained carbides but the other plates solidified without carbides. Metallographic examination showed two populations of graphite nodules. A small group of nodules was larger than rest of the nodules. Color etching revealing the segregation of Si showed a higher Si content in the ferrite around the larger nodules compared to the ferrite around the rest of the nodules. This indicates that solidification took place along the following path: The solidification starts with nucleation and growth of primary graphite nodules. This probably starts during the filling of the mould. The primary nodules act as nuclei for austenite. As austenite easily nucleates on graphite the temperature will be the same for the 3 and 4 mm plate for the first part of the eutectic solidification. This first part of the solidification ends when concentration of carbon around austenite dendrites is too large and new nodules have to nucleate and grow. The larger under cooling for the 3 mm plates compared to the 4 mm indicates that the nucleation of new nodules is governed by kinetics even in very well inoculated melts.
机译:过共晶球墨铸铁是在绿色砂模中铸造的,每个模具中有四个板,厚度分别为1.5、2、3和4 mm。在3mm和4mm板中测量温度。温度曲线表明,共晶凝固分为两个阶段:一次和二次共晶凝固。第一阶段相对较短,没有或几乎没有刷新。进一步在冷却下,然后在重新凝固期间再加热,对于引发共晶凝固的第二部分是必要的。在3mm平板中,二次冷却和二次冷却均大于4mm平板。所有1.5毫米的板都包含碳化物,但其他板固化时没有碳化物。金相检查显示有两个石墨结节。一小组结节大于其余结节。彩色蚀刻揭示了硅的偏析,与其他结核周围的铁素体相比,较大结核周围的铁素体中的硅含量更高。这表明固化是沿着以下路径进行的:固化始于初级石墨结核的成核和生长。这可能是在模具填充期间开始的。初级结节充当奥氏体的核。由于奥氏体容易在石墨上成核,因此对于共晶凝固的第一部分,3mm和4mm板的温度将相同。当奥氏体枝晶周围的碳浓度过大且新的结核必须成核并生长时,固化的第一部分结束。与4mm相比,3mm板在冷却条件下更大,这表明即使在接种得很好的熔体中,新结核的形核也受动力学控制。

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