首页> 外文OA文献 >Effects of Various Substance on the Anhydrous Aluminum Chloride or Allied Catalyst II : Effects of Various Metals and Inorganic Salts on the Aluminum Chloride or Ferric Chloride for the Polymerization of Olefins
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Effects of Various Substance on the Anhydrous Aluminum Chloride or Allied Catalyst II : Effects of Various Metals and Inorganic Salts on the Aluminum Chloride or Ferric Chloride for the Polymerization of Olefins

机译:各种物质对无水氯化铝或相关催化剂的影响II:各种金属和无机盐对氯化铝或氯化铁对烯烃聚合的影响

摘要

In the previous paper, about 10% increase of yields were shown by the addition of many sorts of metals, alloys and inorganic salts to the FeCl_3 a catalyst for the two kinds of the reaction of ketone-synthesis. Now the similar studies on the polymerization of olefins are carried out using AlCl_3 or FeCl_3 catalyst accompanied with various metals or inorganic salts, because these reactions are known to have the mechanism followed by the way of addition with HCl, but not produce HCl as the byproduct differing from the reaction of ketone-synthesis. The results obtained are given in the following summary. (I) Effects of the 13 sorts of metals and 6 sorts of inorganic salts are studied for the polymerization of 3 sorts of olefins i.e. cetene, dodecene and cyclohexene with AlCl_3 or FeCl_3. (II) Many sorts of metals and inorganic salts gave the positive effects, but others of these substance gave the negative effects. (III) These results roughly resembled with the outline for the effect of various metals and inorganic salts in the previous report.
机译:在前一篇论文中,通过向FeCl_3(两种酮合成反应的催化剂)中添加多种金属,合金和无机盐,表明收率提高了约10%。现在,使用AlCl_3或FeCl_3催化剂以及各种金属或无机盐进行类似的烯烃聚合研究,因为已知这些反应具有随后加入HCl的机理,但不会产生HCl副产物。与酮的合成反应不同。下面的摘要中给出了获得的结果。 (I)研究了13种金属和6种无机盐对3种烯烃(即十六碳烯,十二碳烯和环己烯)与AlCl_3或FeCl_3的聚合作用。 (II)多种金属和无机盐起到了积极的作用,但是这些物质中的其他一些给了负面的影响。 (III)这些结果与上一份报告中概述的各种金属和无机盐的影响大致相似。

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