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Pressure screening in the interior of primary shells in double-wall carbon nanotubes

机译:双壁主壳内部的压力筛选   碳纳米管

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摘要

The pressure response of double-wall carbon nanotubes has been investigatedby means of Raman spectroscopy up to 10 GPa. The intensity of the radialbreathing modes of the outer tubes decreases rapidly but remain observable upto 9 GPa, exhibiting a behavior similar (but less pronounced) to that ofsingle-wall carbon nanotubes, which undergo a shape distortion at higherpressures. In addition, the tangential band of the external tubes broadens anddecreases in amplitude. The corresponding Raman features of the internal tubesappear to be considerably less sensitive to pressure. All findings lead to theconclusion that the outer tubes act as a protection shield for the inner tubeswhereas the latter increase the structural stability of the outer tubes uponpressure application.
机译:已经通过拉曼光谱法研究了高达10 GPa的双壁碳纳米管的压力响应。外管的径向呼吸模式的强度迅速降低,但直到9 GPa仍可观察到,表现出与单壁碳纳米管相似的行为(但不太明显),后者在较高压力下会发生变形。另外,外管的切向带在幅度上加宽和减小。内管的相应拉曼特征似乎对压力不那么敏感。所有发现都得出结论,即外管充当内管的保护罩,而内管在施加压力时增加了外管的结构稳定性。

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