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Modelling, Simulation and Sensitivity Analysis of a Fatty Acid MethyludEster Reactive Distillation Process Using Aspen Plus

机译:脂肪酸甲酯的建模,模拟和灵敏度分析使用aspen plus的酯反应蒸馏过程

摘要

Reactive distillation, being an intensified process of combining reaction and distillationudin a single vessel, is an ongoing research. This work considered the use of this novel process toudinvestigate how the purity of a fatty acid methyl ester (oleic acid methyl ester – methyl oleate),udwhich is an alternative fuel that has a potential economic bedrock, vary with variations in refluxudratio and reboiler duty with the aid of Aspen Plus model of the process. The column employed inuddeveloping the model of the process was a RadFrac type having 29 stages, which was divided intoudfive sections, namely condenser (top), rectifying, reaction, stripping and reboiler (bottom) sections.udAfter the development, the model was simulated using UNIversal QUAsiChemical modelud(UNIQUAC) base method. In order to investigate the sensitivity of the system, reflux ratio andudreboiler duty were varied from 2.0-5.5 and 1350-1800 W, respectively. The results obtained fromudthe steady-state simulation of the process revealed that the developed Aspen Plus model of theudsystem was table because it was able to converge when simulated. Furthermore, it was discoveredudfrom the sensitivity analysis carried out that a methyl oleate having a mole fraction ofudapproximately 0.7627 could be obtained from the process when the reflux ratio and the reboilerudduty were 2.0 and 1800 W respectively. Also, it was observed that the mole fraction of methyludoleate was sensitive to both reflux ratio and reboiler duty because the variations in them (refluxudratio and reboiler duty) resulted in corresponding variation in the methyl oleate mole fractionudobtained from the system.
机译:反应蒸馏是将反应和蒸馏结合在单个容器中的强化过程,是一项正在进行的研究。这项工作考虑了使用这种新颖的方法来 ud研究脂肪酸甲酯(油酸甲酯–油酸甲酯)的纯度,这是一种具有潜在经济基础的替代燃料,随回流的变化而变化借助该过程的Aspen Plus模型进行加湿和再沸任务。在开发过程模型中使用的色谱柱为RadFrac型,共有29个阶段,分为五个部分,即冷凝器(顶部),精馏,反应,汽提和再沸器(底部)两个部分。该模型是使用通用拟化学模型 ud(UNIQUAC)基本方法进行模拟的。为了研究系统的灵敏度,回流比和 udreboiler负荷分别在2.0-5.5和1350-1800 W之间变化。从过程的稳态模拟获得的结果表明,开发的系统的Aspen Plus模型是表格,因为它在仿真时能够收敛。此外,从进行的敏感性分析中发现,当回流比和再沸器的负荷分别为2.0和1800W时,可以从该方法中获得摩尔分数为 ud约0.7627的油酸甲酯。另外,观察到仲油酸甲酯的摩尔分数对回流比和再沸器负荷均敏感,因为它们的变化(回流比和再沸器负荷)导致从系统获得的油酸甲酯摩尔分数的相应变化。 。

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