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Production of cenospheres from coal fly ash through vertical thermal flame (VTF) process

机译:通过垂直热火焰(VTF)工艺从煤飞灰中生产空心微珠

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摘要

Coal fly ash is a complex mixture of anthropogenic materials produced during the combustion of pulverised coal in coal fired power plants. They pose environmental concerns that lead to air and water pollution. Effort has been done to reduce the production of coal fly ash or to extract potentially valuable products from coal fly ash, such as cenospheres. Cenospheres are light, low density, thin-walled hollow ceramic microsphere with unique properties. Conventional cenosphere production methods involve the separation of cenospheres from coal fly ash. Due to its small quantities in fly ash (1 % wt.), separation process results in low production of cenospheres. In this work, an attempt by applying a vertical thermal flame (VTF) process is done to produce cenospheres from coal fly ash. Particle size of coal fly ash 63 to 90 μm and 90 to 126 μm are selected to undergo the VTF process. Effect of size of precursor, number of passes through the thermal process, density, morphology and particles size of generated spheres are evaluated. The results show that different sizes of coal fly ash and number of passes through the VTF process affect the morphology of obtained spheres and the overall real density. Further optimization of the VTF process design in terms of heat source and the feeding mechanism are required to increase the transformation of coal fly ash to cenospheres.
机译:粉煤灰是在火力发电厂中粉煤燃烧过程中产生的人为物质的复杂混合物。它们引起环境问题,导致空气和水污染。已经做出努力以减少粉煤灰的生产或从粉煤灰中提取潜在有价值的产品,例如空心层。空心球是具有独特性能的轻质,低密度,薄壁空心陶瓷微球。常规的空心球生产方法涉及从煤粉煤灰中分离空心球。由于其在粉煤灰中的含量很少(1%重量),分离过程导致空心球产量低。在这项工作中,尝试通过应用垂直热火焰(VTF)工艺从粉煤灰生产空心球。选择粉煤灰的粒径63至90μm和90至126μm以进行VTF处理。评估了前驱体尺寸,经过热处理的次数,密度,形态和所生成球体的粒径的影响。结果表明,不同尺寸的粉煤灰和通过VTF过程的通过次数会影响所得球体的形貌和总体真实密度。需要在热源和进料机理方面进一步优化VTF工艺设计,以增加粉煤灰向空心的转化。

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