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Chemical Recycling of Printed Circuit Board Waste by Depolymerization in Sub- and Supercritical Solvents

机译:在亚临界溶剂和超临界溶剂中通过解聚化学回收印刷电路板废料

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摘要

Disposal of waste printed circuit boards is regarded as a potential major environmental problem due to their heavy metal content. Therefore, recycling waste printed circuit boards represents an opportunity to recover the high value resin chemicals and the high value metals that are present. In this study, the solvo-thermal depolymerisation of waste printed circuit boards obtained from desktop computer monitors was carried out using water, ethanol and acetone between 300 and 400 °C. Alkalis (NaOH, KOH) were used as additives to promote the removal of the resin fraction of the printed circuit boards. At 400 °C, 94 % resin removal was achieved when water was used as the solvent, in the presence of NaOH. The liquid produced in the process was analysed by GC/MS and the results showed that it was mainly composed of phenol, and some phenolic compounds, with up to 62.5 wt% present as phenol in the liquid phase.
机译:废弃印刷电路板的处理由于其重金属含量而被视为潜在的主要环境问题。因此,回收废印刷电路板代表了回收存在的高价值树脂化学品和高价值金属的机会。在这项研究中,使用水,乙醇和丙酮在300至400°C之间进行了从台式计算机显示器获得的废印刷电路板的溶剂热解聚。碱(NaOH,KOH)用作添加剂,以促进去除印刷电路板的树脂部分。在NaOH的存在下,以水为溶剂,在400°C时,可去除94%的树脂。用GC / MS分析该过程中产生的液体,结果表明它主要由苯酚和一些酚类化合物组成,液相中苯酚的含量高达62.5 wt%。

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