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Melt volume flow rate and melt flow rate of kenaf fibre reinforced Floreon/magnesium hydroxide biocomposites

机译:洋麻纤维增强的Floreon /氢氧化镁生物复合材料的熔体体积流速和熔体流动速率

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摘要

A study of the melt volume flow rate (MVR) and the melt flow rate (MFR) of kenaf fibre (KF) reinforced Floreon (FLO) and magnesium hydroxide (MH) biocomposites under different temperatures (160–180 °C) and weight loadings (2.16, 5, 10 kg) is presented in this paper. FLO has the lowest values of MFR and MVR. The increment of the melt flow properties (MVR and MFR) has been found for KF or MH insertion due to the hydrolytic degradation of the polylactic acid in FLO. Deterioration of the entanglement density at high temperature, shear thinning and wall slip velocity were the possible causes for the higher melt flow properties. Increasing the KF loadings caused the higher melt flow properties while the higher MH contents created stronger bonding for higher macromolecular chain flow resistance, hence lower melt flow properties were recorded. However, the complicated melt flow behaviour of the KF reinforced FLO/MH biocomposites was found in this study. The high probability of KF–KF and KF–MH collisions was expected and there were more collisions for higher fibre and filler loading causing lower melt flow properties.
机译:不同温度(160–180°C)和重量载荷下洋麻纤维(KF)增强的Floreon(FLO)和氢氧化镁(MH)生物复合材料的熔体体积流量(MVR)和熔体流量(MFR)的研究(2.16、5、10公斤)在本文中介绍。 FLO的MFR和MVR值最低。对于KF或MH插入,已经发现由于在FLO中聚乳酸的水解降解,熔体流动性质(MVR和MFR)的增加。高温下缠结密度的降低,剪切稀化和壁滑速度是造成较高熔体流动性能的可能原因。 KF载荷的增加导致较高的熔体流动性,而较高的MH含量则产生较强的键合,从而具有较高的大分子链流动阻力,因此记录了较低的熔体流动性。但是,在这项研究中发现了KF增强的FLO / MH生物复合材料的复杂熔体流动行为。预计发生KF-KF和KF-MH碰撞的可能性很高,并且较高的纤维和填料载荷会导致更多的碰撞,从而降低熔体流动性。

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