Influence of charge status on the stress safety properties of Li(Ni₁⁄₃Co₁⁄₃Mn₁⁄₃)O₂ cells

摘要

In order to improve safety management, the stress changes of Li(Ni1/3Co1/3Mn1/3)O2 (NMC) cells are real-time monitored using non-destructive strain gauges, and the effects of gauge substrate, temperature and state-of-charge (SOC) have been investigated. The shell exhibits elastic deformation behaviour, and the strain-stress relationship is established. As the temperature increases from 25 to 80 °C, the stress of the NMC cells increases from 0 to 275 MPa, especially greatly at 70 °C and sharply at 80 °C after 18 h. The stress increases from 0 to 9.2 MPa when the potential increases from 2.8 to 4.3 V. However, the value rises from 10 to 55 MPa when the voltage increases from 4.6 to 5.0 V during the over-charge process. An obvious increase of stress appears when the cut-off voltage is below 0.6 V during over-discharge tests. The facile method is significant for non-destructive inspection and emergency management of batteries.