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Process simulation and analysis of carbon capture with an aqueous mixture of ionic liquid and monoethanolamine solvent

机译:用离子液体和单乙醇胺溶剂的含水混合物进行碳捕获的过程模拟和分析

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摘要

This study investigated the prospect of using aqueous mixture of 1-butylpyridinium tetrafluoroborate ([Bpy][BF4]) ionic liquid (IL) and monoethanolamine (MEA) as solvent in post-combustion CO2 capture (PCC) process. This is done by analysis of the process through modelling and simulation. In literature, reported PCC models with a mixture of IL and MEA solvent were developed using equilibrium-based mass transfer approach. In contrast, the model in this study is developed using rate-based mass transfer approach in Aspen Plus®. From the results, the mixed aqueous solvent with 5–30 wt% IL and 30 wt% MEA showed 7%–9% and 12%–27% less specific regeneration energy and solvent circulation rate respectively compared to commonly used 30 wt% MEA solvent. It is concluded that the IL concentration (wt%) in the solvent blend have significant impact on specific regeneration energy and solvent circulation rate. This study is a starting point for further research on technical and economic analysis of PCC process with aqueous blend of IL and MEA as solvent.
机译:本研究探讨了在燃烧后CO2捕集(PCC)过程中使用四氟硼酸1-丁基吡啶鎓([Bpy] [BF4])离子液体(IL)和单乙醇胺(MEA)的水性混合物作为溶剂的前景。这是通过对建模和仿真过程的分析来完成的。在文献中,使用基于平衡的传质方法开发了包含IL和MEA溶剂混合的PCC模型。相反,本研究中的模型是使用AspenPlus®中基于速率的传质方法开发的。根据结果​​,与常用的30 wt%MEA溶剂相比,具有5-30 wt%IL和30 wt%MEA的混合水性溶剂的比再生能量和溶剂循环率分别降低了7%–9%和12%–27% 。结论是,溶剂共混物中的IL浓度(wt%)对比再生能和溶剂循环速率有显着影响。这项研究是进一步研究以IL和MEA的水性混合物为溶剂的PCC工艺的技术和经济分析的起点。

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