Highly polarised white light emission from a hybrid organic/inorganic device has been achieved. The hybrid devices are fabricated by means of combining blue InGaN-based multiple quantum wells (MQWs) with a one-dimensional (1D) grating structure and down-conversion F8BT yellow light emitting polymer. The 1D grating structure converts the blue emission from unpolarised to highly polarised; Highly polarised yellow emission has been achieved from the F8BT polymer filled and aligned along the periodic nano-channels of the grating structure as a result of enhanced nano-confinement. Optical polarization measurements show that our device demonstrates a polarization degree of up to 43% for the smallest nano-channel width. Furthermore, the hybrid device with such a grating structure allows us to achieve an optimum relative orientation between the dipoles in the donor (i.e., InGaN/GaN MQWs) and the diploes in the acceptor (i.e., the F8BT), maximizing the efficiency of non-radiative energy transfer (NRET) between the donor and the acceptor. Time-resolved micro photoluminescence measurements show a 2.5 times enhancement in the NRET efficiency, giving a maximal NRET efficiency of 90%. It is worth highlighting that the approach developed paves the way for the fabrication of highly polarized white light emitters.
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机译:已经实现了来自混合有机/无机装置的高偏振白光发射。通过将具有一维(1D)光栅结构的蓝色基于InGaN的多量子阱(MQW)与降频转换的F8BT黄色发光聚合物相结合来制造混合器件。一维光栅结构将蓝色发射从非偏振转换为高偏振;由于增强的纳米约束,F8BT聚合物沿光栅结构的周期性纳米通道填充并排列后,实现了高度偏振的黄色发射。光学偏振测量结果表明,对于最小的纳米通道宽度,我们的设备显示出高达43%的偏振度。此外,具有这种光栅结构的混合器件使我们能够在施主中的偶极子(即InGaN / GaN MQW)和受体中的偶极子(即F8BT)之间实现最佳相对取向,从而最大程度地提高了非晶体的效率。 -供体和受体之间的辐射能转移(NRET)。时间分辨的微光致发光测量显示NRET效率提高了2.5倍,最大NRET效率为90%。值得强调的是,开发的方法为制造高偏振白光发射器铺平了道路。
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