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Mass transfer in gas-liquid slurry reactors

机译:气液淤浆反应器中的传质

摘要

A critical review is presented on the mass transfer characteristics of gas¿liquid slurry reactors. The recent findings on the influence of the presence of solid particles on the following mass transfer parameters in slurry reactors are discussed: volumetric gas¿liquid mass transfer coefficients (kLa, kGa), liquid-side mass transfer coefficients (kL and kS) and specific gas¿slurry contact area (a). The second part of this paper reviews the recent progress in our knowledge and understanding of the enhancement of gas¿slurry mass transfer due to the presence of solids. Five different cases are distinguished, i.e. udud¿ enhanced mass transfer by physical adsorption on small particles.udud¿ enhanced mass transfer by fast homogeneous reactions in the slurry, due to inert particles,udud¿ enhanced mass transfer by homogenous reaction in the liquid with dissolving particles,udud¿ enhanced mass transfer due to reactive particles andudud¿ enhanced mass transfer due to catalytic particles in heterogeneous reactive systems.ududProspective areas for additional research are identified.
机译:对气液浆反应器的传质特性进行了严格的评述。讨论了固体颗粒的存在对淤浆反应器中以下传质参数的影响的最新发现:体积气体-液体传质系数(kLa,kGa),液体侧传质系数(kL和kS)和比值气体浆接触面积(a)。本文的第二部分回顾了由于固体的存在而使我们对提高气体浆液传质的认识和理解方面的最新进展。有五种不同的情况,即通过小颗粒上的物理吸附提高了传质。由于惰性粒子,浆料中快速的均相反应提高了传质,提高了传质通过在液体中与溶解颗粒的均相反应进行转移,由于反应性颗粒而使传质增强,由于在非均相反应体系中由于催化颗粒而使传质增强。确定。

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