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Equation of state and jamming density for equivalent bi- and polydisperse, smooth, hard sphere systems.

机译:等效双分散和多分散,光滑,硬球系统的状态方程和干扰密度。

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摘要

We study bi- and polydisperse mixtures of hard sphere fluids with extreme size ratios up to 100. Simulation results are compared with previously found analytical equations of state by looking at the compressibility factor, Z, and agreement is found with much better than 1% deviation in the fluid regime. A slightly improved empirical correction to Z is proposed. When the density is further increased, excluded volume becomes important, but there is still a close relationship between many-component mixtures and their binary, two-component equivalents (which are defined on basis of the first three moments of the size distribution). Furthermore, we determine the size ratios for which the liquid-solid transition exhibits crystalline, amorphous or mixed system structure. Near the jamming density, Z is independent of the size distribution and follows a −1 power law as function of the difference from the jamming density (Z → ∞). In this limit, Z depends only on one free parameter, the jamming density itself, as reported for several different size distributions with a wide range of widths.
机译:我们研究极限尺寸比最大为100的硬球形流体的双分散和多分散混合物。通过查看压缩系数Z将模拟结果与先前找到的状态分析方程进行比较,发现相差远大于1%在流体状态。提出了对Z的经验校正的略微改进。当密度进一步增加时,排除体积变得很重要,但是多组分混合物与其二元,二组分当量(它们是根据尺寸分布的前三个时刻定义的)之间仍然存在密切的关系。此外,我们确定了液固转变表现出结晶,非晶或混合体系结构的尺寸比。在干扰密度附近,Z与尺寸分布无关,并且遵循-1幂定律,作为与干扰密度之差(Z→∞)的函数。在此限制下,Z仅取决于一个自由参数,即干扰密度本身,这是针对宽度范围很广的几种不同尺寸分布所报告的。

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  • 作者

    Ogarko V.; Luding S.;

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  • 年度 2012
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  • 原文格式 PDF
  • 正文语种 {"code":"en","name":"English","id":9}
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