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Asymmetric synthesis of 2-alkyl-3-phosphonopropanoic acid derivatives via Rh-catalyzed asymmetric hydrogenation

机译：asymmetric synthesis of 2-alkyl-3-phosphonopropanoic acid derivatives via Rh-catalyzed asymmetric hydrogenation

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The commercially available ferrocene-based diphosphine ligand (S-c,S-Fc)-TaniaPhos was found to be highly effective in the Rh-catalyzed asymmetric hydrogenation of 3-aryl-2-(phosphonomethyl)propenates. Excellent enantioselectivity (90-98% ee) and high catalytic activity (S/C up to 1000) have been achieved, which represents the best results reported so far. (C) 2011 Elsevier Ltd. All rights reserved.

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Luo Li-Bin; Wang Dao-Yong; Zhou Xiao-Mao; Zheng Zhuo; Hu Xiang-Ping;
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年度 2011
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2. Synthesis of New Ligand 1,2-Bis { di( R ,R) -1,3,2-oxzaphosphlidine phosphino} ethane with C2 -symmetric Axis and Application in Rh-catalyzed Asymmetric Hydrogenation [J] . GONG Da-chun, ZHOU Hua, WEI Ping, 高等学校化学研究（英文版） . 2007,第005期
3. Synthesis of Novel C2-Symmetrical Bidentate Phosphoramidite Ligands for Rh-catalyzed Asymmetric Hydrogenation of β-(Acylamino)acrylates [J] . Qing Heng ZENG, Xiang Ping HU, Xin Miao LIANG, 中国化学快报（英文版） . 2006,第006期
4. Asymmetric Hydrogenation Synthesis of (S)-(+)-2-(6′-methoxyl- 2-naphthyl) propionic Acid by Cinchona Modified Pd(0)-α-FeOOH Catalyst [J] . Hong Zhu MA, Bo WANG 中国化学快报（英文版） . 2003,第011期
5. Asymmetric synthesis of 2-alkyl-3-phosphonopropanoic acid derivatives via Rh-catalyzed asymmetric hydrogenation [J] . Luo L.-B., Wang D.-Y., Zhou X.-M., Tetrahedron, Asymmetry: The International Journal for Repid Publication on all Aspects of Asymmetry in Orgainc, Inorganic, Organometallic, Physical and Bio-Organic Chemistry . 2011,第24期

机译：Rh催化的不对称加氢反应不对称合成2-烷基-3-膦酰基丙酸衍生物
6. Asymmetric synthesis of 2-alkyl-3-phosphonopropanoic acids via p-c bond formation and hydrogenation [J] . Badkar PA, Rath NP, Spilling CD Organic letters . 2007,第18期

机译：通过p-c键形成和氢化反应不对称合成2-烷基-3-膦酰基丙酸
7. Asymmetric synthesis of chiral glutaric acid derivatives via Rh-catalyzed enantioselective hydrogenation [J] . Duan Zheng-Chao, Hu Xiang-Ping, Deng Jun, Tetrahedron, Asymmetry: The International Journal for Repid Publication on all Aspects of Asymmetry in Orgainc, Inorganic, Organometallic, Physical and Bio-Organic Chemistry . 2009,第5期

机译：Rh催化对映选择性加氢不对称合成手性戊二酸衍生物
8. Synthesis of Amino Acid Derivatives via Asymmetric Hydrogenation [C] . Hideo Shimizu, Izuru Nagasaki, Noboru Sayo, Asymmetric synthesis and application of α-amino acids . 2007

机译：通过不对称加氢合成氨基酸衍生物
9. I. A1,3- strain enabled retention of chirality during Bis-cyclization of β-ketoamides: Asymmetric synthesis and bioactivity of salinosporamide a and derivatives II. Optimization of an Organic syntheses procedure: asymmetric nucleophile-catalyzed aldol-lactonization with aldehyde acids [D] . Nguyen, Henry 2010

机译：I. A1,3-菌株能够在β-酮基酰胺的双环化过程中保留手性：salinosporamide a和衍生物II的不对称合成和生物活性。有机合成程序的优化：醛酸不对称亲核催化醛醇内酯化
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机译：对映体富集的烯酮异二聚体的催化加氢不对称合成二丙酸酯衍生物
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机译：抗Bophoz型配体的Rh催化不对称氢化对B2-氨基酸的映选择性合成：N-H质子在配体对映选择性的重要影响

Asymmetric synthesis of 2-alkyl-3-phosphonopropanoic acid derivatives via Rh-catalyzed asymmetric hydrogenation

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