Oxidative dehydrogenation of ethane to ethylene over LiCl/MnOx/PC catalysts

摘要

The catalytic stability of LiCl/MnOx/PC catalyst have been investigated, the deactivation mechanism was discussed. The experimental results show that ethane conversion decreases and ethylene selectivity keeps about 90% as reaction time increases. The main deactivation reasons of LiCl/MnOx/PC catalyst for oxidative dehydrogenation of ethane (ODHE) to ethylene are the transition of active species Mn2O3 to MnO species and the loss of arrive component Cl in catalyst. instead of ethane with FCC tailed-gas, the stability of LiCl/MnOx/PC catalyst has been largely improved.