CW and pulsed electrically detected magnetic resonance spectroscopy at 263 GHz 12 T on operating amorphous silicon solar cells

摘要

Here we describe a new high frequency high field continuous wave and pulsed electrically detected magnetic resonance CW EDMR and pEDMR setup, operating at 263 GHz and resonance fields between 0 and 12 T. Spin dependent transport in illuminated hydrogenated amorphous silicon p i n solar cells at 5 K and 90 K was studied by in operando 263 GHz CW and pEDMR alongside complementary X band CW EDMR. Benefiting from the superior resolution at 263 GHz, we were able to better resolve EDMR signals originating from spin dependent hopping and recombination processes. 5 K EDMR spectra were found to be dominated by conduction and valence band tail states involved in spin dependent hopping, with additional contributions from triplet exciton states. 90 K EDMR spectra could be assigned to spin pair recombination involving conduction band tail states and dangling bonds as the dominating spin dependent transport process, with additional contributions from valence band tail and triplet exciton states