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Effect of Material and Process Atmosphere in the Preparation of Al-Ti-B Grain Refiner by SHS

机译:sHs制备al-Ti-B晶粒细化剂中材料和工艺气氛的影响

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摘要

Al-Ti-B master alloys are widely used in the aluminum industry as grain refiners for the control of the microstructure of the aluminum alloys. The SHS (self-propagating high-temperature synthesis) is an ex situ method that uses exothermic reactions to sustain the chemical reaction in a combustion wave. The advantages of SHS are the low energy requirement, simplicity and product purity. However, the raw material used has to be very pure, with a very small size leading to the necessity of a reactor with a protective gas to produce the reaction. The purpose of this investigation is to fabricate SHS master alloys with commercial standard raw materials, with lower purity and higher grain size without a reactor or protective gas in order to (1) decrease the price and (2) improve the productivity of master alloy manufacturing. The possibility of using cheap borated salts instead of expensive pure boron has been studied. Different compositions of aluminum master alloy have been developed. Bigger TiB2 grain size has been obtained when using bigger commercial raw materials. Larger titanium powder can produce an aluminum master alloy with a maximum of 30% of aluminum without reactor. In comparison, SHS reaction is much more difficult when using finer titanium powder.
机译:Al-Ti-B中间合金广泛用于铝工业中,作为晶粒细化剂,用于控制铝合金的微观结构。 SHS(自蔓延高温合成)是一种非原位方法,它使用放热反应来维持燃烧波中的化学反应。 SHS的优点是能耗低,简单且产品纯度高。然而,所使用的原料必须非常纯净,具有非常小的尺寸,导致需要具有保护性气体的反应器来进行反应。这项研究的目的是使用商业标准原料制造SHS中间合金,而无需使用反应器或保护性气体,其纯度较低,晶粒尺寸较大,以便(1)降低价格,(2)提高中间合金的生产效率。已经研究了使用廉价的硼酸盐代替昂贵的纯硼的可能性。已经开发了铝中间合金的不同组成。使用较大的商业原料时,可以获得更大的TiB2晶粒尺寸。较大的钛粉可以在不使用反应器的情况下生产含铝量最多为30%的铝中间合金。相比之下,当使用更细的钛粉时,SHS反应要困难得多。

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