Since conventional anti-slip enamels show some disadvantages, directly related to the surface roughness which prevents the adequate surface cleaning of tile, an anti-slip enamel exhibiting glass-ceramic nature has been designed, characterized by being stain-resistant and presenting a smooth texture and touch soft. To do this, new matte frits and raw materials with similar nature have been used, refractory enough to be suitable in enamel compositions for porcelain stoneware. The glass-ceramic glaze thus prepared was characterized by various instrumental techniques (X-ray fluorescence [XRF], scanning electron microscopy [SEM], X-ray diffraction [XRD], mechanical profilometry and microhardness measurements), in order to check the nature of crystallized phases, their morphology, surface roughness and microhardness of the finished tile. In addition, the quality of the glazed piece has been evaluated by the regulations of chemical resistance, stain-resistance and slipperiness. The enamel obtained has devitrified in crystals of silicoaluminates of calcium and barium and complies with standards of anti-slip and stain-resistence, as it has a surface roughness similar to a non-slip enamel.
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