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Numerical simulations of pyrolysis of wet charring materials using a one-dimensional enthalpy based model

机译:用一维焓基模型对湿炭化材料热解的数值模拟

摘要

Solid phase modelling coupled to gas phase combustion of volatiles helps to investigate the flame spread over solids. The present work focuses on the solid phase. Numerical simulations of pyrolysis of wet charring materials are performed. When the solid is exposed to an external heat flux, the model is such that the moisture present first flows out, leaving behind dry solid. This solid then further heats up and finally generates a mass flow rate of combustible volatiles during the 'pyrolysis' process, i.e. the degradation of the solid. Evaporation and pyrolysis, possibly occurring at the same time, are assumed to take place in infinitely thin fronts. Pyrolysis is thus modelled as an infinitely fast, irreversible endothermic process at the 'pyrolysis temperature' (Tpyr) and as such, all kinetics are ignored. The cases considered are one-dimensional in nature, in order to focus on the principal model performance. Enthalpy is the basic model variable. The temperature distribution inside the material, along with the evaporation and pyrolysis front positions, are related to the distribution of enthalpy. A piecewise linear temperature field representation is adopted.
机译:固相建模与挥发物的气相燃烧相结合有助于研究火焰在固体上的扩散。目前的工作集中在固相。进行了湿法炭化材料热解的数值模拟。当固体暴露于外部热流中时,模型将使存在的水分首先流出,而留下干燥的固体。然后,该固体进一步加热,并最终在“热解”过程中产生可燃挥发物的质量流率,即固体的降解。可能同时发生的蒸发和热解发生在无限薄的前沿。因此,热解被建模为在“热解温度”(Tpyr)下无限快速,不可逆的吸热过程,因此,所有动力学都被忽略了。考虑的案例本质上是一维的,以便专注于主要模型的性能。焓是基本模型变量。材料内部的温度分布以及蒸发和热解的前沿位置与焓的分布有关。采用分段线性温度场表示。

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