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Preparation of cycloaliphatic epoxy hybrids with non-conventional amine-curing agent

机译:用非常规胺固化剂制备脂环族环氧杂化物

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摘要

Cycloaliphatic epoxy resin has been successfully thermally cured using a polyamino siloxane oligomer as hardener. The curing reaction was followed by infrared spectroscopy in the near range, and thermal transitions were measured by dynamic mechanical thermal analysis. The use of accelerants and a plasticizer (dodecylphenol), and different curing schedules were explored. Cured materials showed high Tg values (around 125&-164 °C), and the analysis of laser scanning confocal microscopy images showed that they are homogeneous in the microscale.
机译:脂环族环氧树脂已成功地使用聚氨基硅氧烷低聚物作为固化剂进行了热固化。固化反应之后,在近范围内进行红外光谱分析,并通过动态机械热分析测量热转变。探索了促进剂和增塑剂(十二烷基苯酚)的使用以及不同的固化时间表。固化材料显示出较高的Tg值(约125和-164°C),对激光扫描共聚焦显微镜图像的分析表明它们在微观尺度上是均匀的。

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