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Composite polímero-corcho para la fabricación de tapones de botellas de vino mediante moldeo por inyección

机译:复合聚合物软木塞,用于通过注塑制造葡萄酒瓶盖

摘要

In a previous work composites polymer/cork for the production of wine closures by injection moulding were developed. This new material exhibited good flow behaviour during moulding and suitable mechanical properties. However some critical aspects such as dark coloration of final product, porosity and hardness should be improved.For these reasons the aim of this work was to study the causes of dark coloration in cork composite and to improve hardness without to lose too much of the tensile strength.First, to study thermal degradation of cork and composite thermal treatment was carried out by differential scanning calorimetric (DSC), thermo gravimetrical analyses (TGA) and conventional furnaces.Then blends were prepared in a twin screw extruder. Cork content was 40 vol%. The matrix consisted in 55 vol% of LDPE/PW in volume relation of 90/10, 70/30 and 50/50. 5 vol% of Stearic acid was coated onto cork surface to improve flow behaviour and the interaction between cork and polymer.Injection stage was carried out and parameters such as temperature, injection volume and speed were optimized.Mechanical properties of final parts were tested. Tensile strength of samples ranged between3.21 and 7.4 MPa. On the other hand hardness ranged between 40 and 50 Shore D been these values better than composites without paraffin wax.Finally it was concluded that PW has a positive effect on thermal characteristics of blends allowing processing the mixtures at lower temperature avoiding thermal degradation of cork. Besides wax also proved to enhance flow behaviour of mixtures and to lower the harness of final parts what is desirable for final application.
机译:在先前的工作中,开发了用于通过注模生产酒盖的聚合物/软木复合材料。这种新材料在成型过程中表现出良好的流动性能,并具有合适的机械性能。但是,应改善一些关键方面,例如最终产品的深色,孔隙率和硬度。因此,本工作的目的是研究软木复合材料中深色的原因,并在不损失太多拉伸强度的情况下提高硬度。首先,通过差示扫描量热法(DSC),热重分析(TGA)和常规熔炉对软木的热降解和复合热处理进行研究,然后在双螺杆挤出机中制备共混物。软木含量为40体积%。基质由55体积%的LDPE / PW组成,体积比为90 / 10、70 / 30和50/50。在软木表面涂上5 vol%的硬脂酸以改善流动性能以及软木与聚合物之间的相互作用。进行注射阶段,并优化温度,注射量和速度等参数,并测试最终零件的机械性能。样品的拉伸强度在3.21和7.4 MPa之间。另一方面,肖氏D硬度在40至50之间,比不使用石蜡的复合材料要好。最后,结论是PW对共混物的热特性有积极影响,可以在较低的温度下加工混合物,避免软木塞的热降解。此外,蜡还被证明可以增强混合物的流动性能并降低最终零件的线束,这是最终应用所需要的。

著录项

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    Imboden Martin;

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  • 年度 2009
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  • 原文格式 PDF
  • 正文语种 eng
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