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Nonlinear orthotropic model of the inhomogeneous assembly compression of PEM fuel cell gas diffusion layers

机译:pEm燃料电池气体扩散层非均匀组装压缩的非线性正交各向异性模型

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摘要

PEM fuel cell assembly pressure is known to cause large strains in the gas diffusion layer (GDL), which results in significant changes in its mechanical, electrical and thermal properties. These changes affect the rates of mass, charge, and heat transport through the GDL, thus impacting fuel cell performance and lifetime. The appropriate modeling of the inhomogeneous GDL compression process associated with the repetitive channel rib pattern is therefore essential for a detailed description of the physical chemical processes that take place in the cell. In this context, the mechanical characterization of the GDL is of special relevance, since its microstructure based on carbon fibers has strongly nonlinear orthotropic properties. The present study describes a new finite element model which fully incorporates the nonlinear orthotropic characteristics of the GDL, thereby improving the prediction of the inhomogeneous compression effects in this key element of the cell. Among other conclusions, the numerical results show that the linear isotropic models widely reported in the literature tend to overestimate the porosity and the partial intrusion of the GDL in the channel region, and may lead to incorrect predictions in terms of interfacial contact pressure distributions.
机译:众所周知,PEM燃料电池组件的压力会在气体扩散层(GDL)中引起较大的应变,从而导致其机械,电气和热性能发生重大变化。这些变化会影响通过GDL的质量,电荷和热量传输的速率,从而影响燃料电池的性能和寿命。因此,与重复通道肋图案相关的不均匀GDL压缩过程的适当建模对于细胞中发生的物理化学过程的详细描述至关重要。在这种情况下,GDL的机械特性具有特殊意义,因为其基于碳纤维的微结构具有强烈的非线性正交各向异性。本研究描述了一种新的有限元模型,该模型充分结合了GDL的非线性正交各向异性特征,从而改善了该单元关键元素中非均匀压缩效应的预测。除其他结论外,数值结果还表明,文献中广泛报道的线性各向同性模型往往会高估通道区域中GDL的孔隙度和部分侵入,并可能导致界面接触压力分布方面的错误预测。

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