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Changes in the phase composition in OPC and blended cement mortars due to carbonation

机译:由碳酸化引起的OpC和混合水泥砂浆中相组成的变化

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摘要

The effect of carbonation on the phase composition in salt-contaminated (0.8% Cl- and 1.5% S03) anduduncontaminated OPC and blended cement mortar specimens exposed to elevated temperature is described.udChanges in the phase composition were monitored using X-ray diffraction and differential thermal/udthermogravimetric analyses. Results indicated the transformation of cement hydration products to calcite inudOPC, while calcite and aragonite were detected in the blended cements. The quantity of calcium carbonate in theudcontaminated cements was more than that in the uncontaminated specimens. The enhanced carbonation in theudcontaminated specimens may by attributed to: (i) an increase in the alkalinity of the pore solution; and (ii)udchanges in the morphology of the hardened cement, brought about by the chloride-sulfate contamination.
机译:描述了碳化对盐污染(0.8%Cl-和1.5%SO3)和 udun污染的OPC以及暴露在高温下的水泥砂浆标本中相组成的影响。 ud使用X射线监测相组成的变化衍射和差示热/热重分析。结果表明,水泥水化产物在 udOPC中转变为方解石,而在掺合水泥中检测到方解石和文石。受过污染的水泥中的碳酸钙含量高于未受污染的样品中的碳酸钙含量。受到污染的标本中碳酸的增加可能归因于:(i)孔溶液碱度的增加; (ii)氯化物硫酸盐污染导致硬化水泥的形态发生变化。

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