Complete Series of Chiral Paramagnetic Molecular Conductors Based on Tetramethyl-bis(ethylenedithio)-tetrathiafulvalene (TM-BEDT-TTF) and Chloranilate-Bridged Heterobimetallic Honeycomb Layers

摘要

This article reports on the crystal structure and the physical properties of a complete series of isostructural chiral molecular conductors obtained combining the TM-BEDT-TTF organic donor as (S,S,S,S) and (R,R,R,R) enantiopure forms, or racemic mixture (rac), with heterobimetallic anionic layers obtained “in situ” by the self-assembling of tris(chloranilato)ferrate(III) metal complexes and potassium cations.