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Influence of europium (Eu3+) ions on the optical properties of silver lead borate glasses

机译:铕(Eu3 +)离子对银硼酸铅玻璃光学性质的影响

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摘要

The influence of europium (Eu3+) ions on the optical properties of silver lead borate glasses of the xEu2O3–(1 – x)Ag2O–29PbO–70B2O3 (x = 0, 0.1, 0.2, 0.3, 0.4 and 0.5 mol%) glass system prepared by theconventional melt quenching technique and their physical and optical properties were investigated. The UV absorption spectra were recorded at room temperature in the wavelength range of 200–600 nm. From the absorption edge data, it is found that both the direct and indirect transitions and their values are ranging from 3.19 to 3.54 and 2.50 to 3.07 eV, respectively. The Urbach energy values for these glasses were found to be in the range of 0.39–0.52 eV. The refractive indices have also been evaluated with respect to different molar concentrations of Eu2O3 and their calculated values are ranging from 1.598 to 1.654.
机译:((Eu3 +)离子对xEu2O3–(1–x)Ag2O–29PbO–70B2O3(x = 0、0.1、0.2、0.3、0.4和0.5 mol%)玻璃硼酸银玻璃的光学性能的影响用常规熔体淬火技术制备了它们的物理和光学性质。在室温下在200–600 nm的波长范围内记录紫外线吸收光谱。从吸收边缘数据中发现,直接和间接跃迁及其值分别在3.19至3.54和2.50至3.07 eV的范围内。发现这些玻璃的Urbach能量值在0.39–0.52 eV的范围内。还针对不同摩尔浓度的Eu2O3评估了折射率,其计算值范围为1.598至1.654。

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    Keshavamurthy K.; Eraiah B.;

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  • 年度 2015
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  • 原文格式 PDF
  • 正文语种 en
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