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Comparison of catalyst activity between palladium, copper and iron catalyst in catalytic combustion of methane

机译:钯,铜,铁催化剂在甲烷催化燃烧中的催化活性比较

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摘要

Catalyst used for high-temperature combustion of light hydrocarbon for example methane must maintain high activity over long time intervals by avoiding excessive sintering and deactivation in the hot and corrosive combustion environment. This study is carried out to compare the catalyst activity between Palladium, Iron and Copper catalyst in the catalytic combustion of methane. The characteristics of catalyst are studied with NA and SEM. In this characterization method, the catalyst morphology and the surface areas of the catalyst can study. This research is carried out in the micro reactor in laboratory scale. The effect of Hydrogen Sulphide, H2S poisoning on the combustion of methane over alumina-supported' also investigates. From the result obtain, PdfAh03 is the most active catalyst and stable follow by CulAh03 and Fe/Ah03. BET characterization shows that, all catalyst loss its specific surface area when poison with H2S and increase follow the order Pd > Cu > Fe.
机译:用于轻质烃(例如甲烷)高温燃烧的催化剂必须避免在高温和腐蚀性燃烧环境中过度烧结和失活,从而长时间保持高活性。本研究旨在比较钯,铁和铜催化剂在甲烷催化燃烧中的催化活性。用NA和SEM研究了催化剂的特性。在这种表征方法中,可以研究催化剂的形态和催化剂的表面积。这项研究是在实验室规模的微型反应器中进行的。还研究了硫化氢,H2S中毒对氧化铝负载的甲烷燃烧的影响。从获得的结果来看,PdfAh03是活性最高的催化剂,其次是CulAh03和Fe / Ah03。 BET表征表明,当催化剂被H2S毒化时,所有催化剂都失去其比表面积并以Pd> Cu> Fe的顺序增加。

著录项

  • 作者

    Nasri Noor Shawal; Tade O. G.;

  • 作者单位
  • 年度 2008
  • 总页数
  • 原文格式 PDF
  • 正文语种 {"code":"en","name":"English","id":9}
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