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Maleic anhydride polyethylene octene elastomer toughened polyamide 6/polypropylene nanocomposites : mechanical and morphological properties

机译:马来酸酐聚乙烯辛烯弹性体增韧聚酰胺6 /聚丙烯纳米复合材料:力学和形态学性能

摘要

A series of polyamide 6/polypropylene (PA6/PP) blends and nanocompo-sites containing 4 wt% of organophilic modified montmorillonite (MMT) were designed and prepared by melt compounding followed by injection molding. Maleicanhydride polyethylene octene elastomer (POEgMAH) was used as impact modifier aswell as compatibilizer in the blend system. Three weight ratios of PA6/PP blends were prepared i.e. 80:20, 70:30, and 60:40. The mechanical properties of PA6/PP blends and nano composite were studied through flexural and impact properties. Scanning electron microscopy (SEM) was used to study the micro structure. The incorporation of 10 wt% POEgMAH into PA6/PP blends significantly increased the toughness with a corresponding reduction in strength and stiffness. However, on further addition of 4wt% organoclay, the strength and modulus increased but with a sacrifice in impact strength. It was also found that the mechanical properties are a function of blend ratio with 70:30 PA6/PP having the highest impact strength, both for blends and nano composites. The morphological study revealed that within the blend ratio studied, the higher the PA6 content, the finer were the POEgMAH particles.
机译:设计并制备了一系列聚酰胺6 /聚丙烯(PA6 / PP)共混物和含有4 wt%亲有机性改性蒙脱土(MMT)的纳米复合位点,方法是熔融共混然后注塑。马来酸酐聚乙烯辛烯弹性体(POEgMAH)在共混体系中用作抗冲改性剂和增容剂。制备了三种重量比的PA6 / PP共混物,即80∶20、70∶30和60∶40。通过弯曲和冲击性能研究了PA6 / PP共混物和纳米复合材料的机械性能。扫描电子显微镜(SEM)用于研究微观结构。将10 wt%POEgMAH加入PA6 / PP共混物中可显着提高韧性,并相应降低强度和刚度。然而,进一步添加4wt%的有机粘土,虽然强度和模量增加,但是冲击强度有所降低。还发现,对于共混物和纳米复合材料,机械性能是具有最高冲击强度的70:30 PA6 / PP的共混比的函数。形态学研究表明,在所研究的混合比内,PA6含量越高,POEgMAH颗粒越细。

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