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Synthesis of new biopolymer-coated manganese-zinc ferrite nanocomposites via coprecipitation method

机译:共沉淀法合成新型生物聚合物包覆的锰锌铁氧体纳米复合材料

摘要

Ferrites are important nanomagnetic materials in chemical industry. Due to their high applicability in pharmaceutical and electronic devices fabrication , these materials have been widely .' investigated. Amongst , manganese and zinc doped ferrite (Mn/Zn ferrite) nanocomposites have attracted intensive attraction of the researchers because of their relatively high magnetic properties . However, magnetic behavior and Van der Waals forces existed in the Mn/Zn ferrite nanocomposites have make the materials naturally amalgamate , leading to reducing of magnetic properties and limitation in their application. In this research, Mn/Zn ferrite was synthesized via chemical co-precipitation , a relatively simple and economical method. In order to study the effect of zinc content towards the magnetic activity, the materials MnxZn1-xFez04 ;x= 1.0, 0.8, 0.6, 0.4, 0.2, 0.1 were synthesized at 7SoC and pH 11. The samples were characterized by X-ray diffraction (XRD) and Field emission scanning electron microscopy (FESEM) techniques. Results indicated that the prepared MnxZn1-xFez04were crystallined in spinel cubic structure with particle size ranged 10-19 nm. Besides, the doping of Zn ions into ferrite structure resulted in the reduction of both crystallinity and crystallite size. Further characterizations will be carried out using Transmission electron microscopy (TEM), Fourier transforms Infrared (FTIR) spectrophotocopy, and Vibrating Sample Magnetometry (VSM) techniques. In order to prevent formation of agglomerat ion among the nanoparticles , coating of Mn/Zn ferrite magnetic nanoparticles using biopolymer such as poly(ethylene glycol) (PEG) and poly(vinyl alcohol) (PVA) will be done. It is believed that both stability and magnetic properties of the modified ferrites will be enhanced significantly after the biopolymer coating.
机译:铁氧体是化学工业中重要的纳米磁性材料。由于它们在制药和电子设备制造中的高度适用性,这些材料已得到广泛应用。调查。其中,锰锌掺杂铁氧体(Mn / Zn铁氧体)纳米复合材料具有较高的磁性能,吸引了研究者的广泛关注。但是,Mn / Zn铁氧体纳米复合材料中存在的磁性和范德华力使材料自然地融合,导致磁性降低,应用受到限制。在这项研究中,Mn / Zn铁氧体是通过化学共沉淀法合成的,这是一种相对简单且经济的方法。为了研究锌含量对磁性的影响,在7SoC和pH 11下合成了MnxZn1-xFez04; x = 1.0、0.8、0.6、0.4、0.2、0.1的材料。样品用X射线衍射表征(XRD)和场发射扫描电子显微镜(FESEM)技术。结果表明,所制备的MnxZn1-xFez04结晶为尖晶石立方结构,粒径为10-19 nm。此外,将锌离子掺杂到铁素体结构中导致结晶度和晶粒尺寸的减小。将使用透射电子显微镜(TEM),傅立叶变换红外(FTIR)分光镜和振动样品磁强计(VSM)技术进行进一步的表征。为了防止在纳米颗粒之间形成团聚离子,将使用生物聚合物例如聚(乙二醇)(PEG)和聚(乙烯醇)(PVA)涂覆Mn / Zn铁氧体磁性纳米颗粒。相信在生物聚合物涂层之后,改性铁氧体的稳定性和磁性能都将显着提高。

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