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Rubber-toughened polyamide 6 / polypropylene nanocomposites: The effect of maleated polyethylene-octene elastomer on the morphological and mechanical properties

机译:橡胶增韧聚酰胺6 /聚丙烯纳米复合材料:马来酸化聚乙烯辛烯弹性体对形态和机械性能的影响

摘要

A series of blends constituted by a polyamide 6 (PA6) and polypropylene (PP) matrix (70:30) added with 4wt% of organophilic modified montmorillonite (MMT) and 10% of maleated polyethylene-octene elastomer (POE-g-MA) were prepared using a co-rotating twin-screw extruder followed by injection molding. POE-g-MA was used as impact modifier. The mechanical properties of the blends were studied through tensile, flexural and impact test. Scanning electron microscopy (SEM) and X-ray diffraction (XRD) was used to assess the blends morphology and to characterize the formation of nanocomposites respectively. Incorporation of the POE-g-MA elastomer into the blends significantly increased the toughness. However, the strength and stiffness were slightly decreased with increasing the concentration of POE-g-MA elastomer. In the POE-g-MA compatibilized PA6/PP nanocomposites, uniform dispersion of POE-g-MA in matrix has been observed through SEM which provide a good improvement of the compatibility between PA6, PP and organoclay. XRD result revealed that PA6/PP nanocomposites were successfully formed and the organoclay were dispersed more uniformly in the presence of POE-g-MA.
机译:由聚酰胺6(PA6)和聚丙烯(PP)基体(70:30)组成的一系列共混物,其中添加了4wt%的亲有机性改性蒙脱土(MMT)和10%的马来酸化聚乙烯辛烯弹性体(POE-g-MA)使用同向双螺杆挤出机,随后进行注射成型,制备出制备的产品。 POE-g-MA用作抗冲改性剂。通过拉伸,弯曲和冲击试验研究了共混物的机械性能。扫描电子显微镜(SEM)和X射线衍射(XRD)用于评估共混物的形态并表征纳米复合材料的形成。将POE-g-MA弹性体掺入共混物中可显着提高韧性。但是,强度和刚度随POE-g-MA弹性体浓度的增加而略有降低。在POE-g-MA相容的PA6 / PP纳米复合材料中,通过SEM观察到POE-g-MA在基质中的均匀分散,这很好地改善了PA6,PP和有机粘土之间的相容性。 XRD结果表明,在POE-g-MA存在下,成功形成了PA6 / PP纳米复合材料,有机粘土更均匀地分散。

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