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Comparison of catalyst activity between palladium,copper, and iron catalyst in catalytic combustion of methane

机译:钯,铜和铁催化剂在甲烷催化燃烧中的催化活性比较

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摘要

Catalyst used for high-temperature combustion of light hydrocarbon for example methaneudmust maintain high activity over long time intervals by avoiding excessive sintering anduddeactivation in the hot and corrosive combustion environment. This study is carried out toudcompare the catalyst activity between Palladium, Iron and Copper catalyst in the catalyticudcombustion of methane. The characteristics of catalyst are studied with NA and SEM. In thisudcharacterization method, the catalyst morphology and the surface areas of the catalyst canudstudy. This research is carried out in the micro reactor in laboratory scale. The effect c4IudHydrogen Sulphide, H2S poisoning on the combustion of methane over alumina-supported'udalso investigates. From the result obtain, PdfAh03 is the most active catalyst and stableudfollow by CulAh03 and Fe/Ah03. BET characterization shows that, all catalyst loss itsudspecific surface area when poison with H2S and increase follow the order Pd > Cu > Fe.
机译:用于轻质烃(例如甲烷)高温燃烧的催化剂必须避免在炎热和腐蚀性燃烧环境中过度烧结和减活化,从而在较长的时间间隔内保持高活性。进行本研究以比较钯,铁和铜催化剂在甲烷催化燃烧中的催化活性。用NA和SEM研究了催化剂的特性。在这种表征方法中,可以研究催化剂的形态和催化剂的表面积。这项研究是在实验室规模的微型反应器中进行的。还研究了硫化氢,硫化氢中毒对氧化铝负载的甲烷燃烧甲烷的影响。从获得的结果来看,PdfAh03是最活泼的催化剂,并且是CulAh03和Fe / Ah03稳定的化合物。 BET表征表明,当催化剂被H2S毒化时,所有催化剂损失其比表面积并按Pd> Cu> Fe的顺序增加。

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