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Catalytic conversion of palm oil to gasoline over H-ZSM-5: effect of temperature and hydrotreatment of catalystsud

机译:H-ZSM-5上棕榈油的催化转化为汽油:温度和催化剂加氢处理的影响 ud

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摘要

Catalytic conversion of palm oil to gasoline was performed over H-ZSM-5 zeolite catalyst. Palm oil was converted in a down flow fixed bed reactor at atmospheric pressure and weight hourly space velocity (WHSV) of 2.5 h-1. Temperature was varied in the range of 450-525°C and hydrogen flow rate for activation of 1-2 L/h. Increasing reaction temperature to 500°C increased the conversion of palm oil. OLP yield and gasoline selectivity increased with temperature until 500°C before decreasing slightly. Hydrotreatment of catalysts increased OLP and gasoline formation while coke and gas decreased. However, increasing the hydrotreating flow rate more than 1L/h gave little effect towards palm oil cracking activity.
机译:在H-ZSM-5沸石催化剂上将棕榈油催化转化为汽油。棕榈油在大气压下以2.5 h-1的重时空速(WHSV)在下行固定床反应器中转化。温度在450-525°C范围内变化,氢气流速为1-2 L / h激活。将反应温度提高到500°C,可以提高棕榈油的转化率。直到500°C,OLP收率和汽油选择性随温度增加而有所降低。催化剂的加氢处理增加了OLP和汽油的形成,而焦炭和气体减少了。然而,将加氢处理流速增加至大于1L / h对棕榈油裂化活性几乎没有影响。

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