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Development of gas separation system by membranes - Preliminary results of membranes characterization

机译:膜法气体分离系统的开发-膜法表征的初步结果

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摘要

The huge natural gas found in Malaysia has necessitated research and development in new technologies of gas processing. Membranes technology is not only the latest and most advanced system but also requires less cost of maintenance. This paper presents the preliminary results of membrane characterization for CO2 separation from natural gas. It is a part of the overall project to develop CO2 gas separation system using membrane from natural gas funded by IRPA.ududPolymeric membrane suitable for gas separation was developed from polymer solution casted on glass plate. Phase inversion technique was then used which produced asymmetric membranes with a very thin skin on top of porous substrate.ududThe asymmetric stucture is an essential properties for high flux and high selectivity required for gas separation. The membranes were then characterized in term of their structure using a Scanning Electron Microscope (SEM). A gas permeation cell was then used to measure the pure gas permeation rates through the membranes.ududPreliminary results of membranes characterization show that asymmetric structure was successfully produced within layer of skin deposited on the porous substrate. However the skin thickness needs to be reduced before a good membrane performance can be obtained as evidenced by the flux measurement data obtained.ududWork is currently focused on the parameters such as temperature and annealing process which influenced the formation of ultra thin skin on top of porous substrate.
机译:在马来西亚发现的巨大天然气需要进行天然气处理新技术的研究和开发。膜技术不仅是最新,最先进的系统,而且需要的维护成本更低。本文介绍了从天然气中分离CO2的膜表征的初步结果。使用IRPA资助的天然气膜开发CO2气体分离系统是整个项目的一部分。 ud ud适用于气体分离的聚合物膜是由浇铸在玻璃板上的聚合物溶液开发而成的。然后使用相转化技术,该技术在多孔基质的顶部生产出具有非常薄表皮的不对称膜。 ud ud不对称结构是气体分离所需的高通量和高选择性的基本特性。然后使用扫描电子显微镜(SEM)根据膜的结构对其进行表征。然后使用气体渗透池测量通过膜的纯气体渗透率。膜表征的初步结果表明,成功地在沉积在多孔基质上的皮肤层内产生了不对称结构。然而,如获得的通量测量数据所证明的那样,在获得良好的膜性能之前需要降低皮肤的厚度。 ud ud目前的工作重点是影响温度和退火工艺等参数,这些参数会影响皮肤上超薄皮肤的形成。多孔基材的顶部。

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